Difference between revisions of "Alumina"

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'''Alumina''' is the chemical <math>Al_2O_3</math>, or aluminium(III) oxide. It occurs naturally as hexagonal crystals called '''corundum''', the second hardest [[mineral]] on Earth.<ref name=Cairncross>B. Cairncross - ''Field guide to rocks and minerals of Southern Africa'' 2004. ISBN 978-1-86872-985-2 pp. 80-82</ref> Used without qualification, '''aluminium oxide''' usually refers to alumina rather than the other oxides of aluminium.
  
'''Alumina''' is the chemical <math>Al_2O_3</math>. It occurs naturally as hexagonal crystals called '''corundum''', the second hardest [[mineral]] on Earth.<ref name=Cairncross>''Field guide to rocks and minerals of Southern Africa'' - B. Cairncross. 2004. ISBN 978-1-86872-985-2</ref>
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==Characteristics==
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The hardness of corundum by definition 9 on Mohs' scale and it has a white streak and vitreous lustre.<ref name=Cairncross />. Corundum has a specific gravity between 3.96<ref name=WebsterJobbins>R. Webster & E.A. Jobbins - ''Gemmologists' compendium'' 7th ed. 2001. ISBN 978-0-7198-0291-1 p. 36.</ref> and 4.1<ref name=Cairncross />. The different varieties have refractive indices varying from between 1.759 and 1.767 to between 1.770 and 1.779.<ref name=WebsterJobbins>R. Webster & E.A. Jobbins - ''Gemmologists' compendium'' 7th ed. 2001. ISBN 978-0-7198-0291-1 p. 36.</ref><br />
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Some corundum, including all rubies, display ''asterism'', which is to say that they reflect light in such a way as to form a six-sided star.<ref name=Cairncross /><ref name=WebsterJobbins />
  
The hardness of corundum by definition 9 on Mohs' scale and it has a white streak, vitreous lustre and specific gravity between 4.0 and 4.1<ref name=Cairncross />. It is used as an abrasive and the production of [[refractory]].
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==Variants==
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The colour of a corundum crystal depends on impurities.
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* Red corundum is known as '''ruby'''.
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* Blue corundum is known as '''sapphire'''. It gets its colour from iron and titanium impurities<ref name=Cairncross />
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* Colourless (pure) corundum is known as '''white sapphire'''.
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* Other varieties of corundum crystal are known by ''colour'' sapphire. These are pink, yellow, violet and green sapphire<ref name=Cairncross />.
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==Occurence==
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On Earth, corundum mainly occurs in [[metamorphic rock]], as well as in [[alluvial deposits]].<ref name=Cairncross />
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==Use==
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* It is used as an [[abrasive]].<ref name=Cairncross />
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* Used in the production of [[refractory]].<ref name=Cairncross />
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* Ruby [[laser|lasers]] are based around synthetic ruby crystals, portions of which are doped with [[chromium]].
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* Alumina can be used as an [[aluminium ore]].
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* Both natural and synthetic corundum is used in jewelry.
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* As a catalyst in the [[Sabatier process]].
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==Open issues==
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* How common are alumina deposits on Mars?
  
 
==References==
 
==References==

Revision as of 11:03, 16 February 2013

Alumina is the chemical , or aluminium(III) oxide. It occurs naturally as hexagonal crystals called corundum, the second hardest mineral on Earth.[1] Used without qualification, aluminium oxide usually refers to alumina rather than the other oxides of aluminium.

Characteristics

The hardness of corundum by definition 9 on Mohs' scale and it has a white streak and vitreous lustre.[1]. Corundum has a specific gravity between 3.96[2] and 4.1[1]. The different varieties have refractive indices varying from between 1.759 and 1.767 to between 1.770 and 1.779.[2]
Some corundum, including all rubies, display asterism, which is to say that they reflect light in such a way as to form a six-sided star.[1][2]

Variants

The colour of a corundum crystal depends on impurities.

  • Red corundum is known as ruby.
  • Blue corundum is known as sapphire. It gets its colour from iron and titanium impurities[1]
  • Colourless (pure) corundum is known as white sapphire.
  • Other varieties of corundum crystal are known by colour sapphire. These are pink, yellow, violet and green sapphire[1].

Occurence

On Earth, corundum mainly occurs in metamorphic rock, as well as in alluvial deposits.[1]

Use

Open issues

  • How common are alumina deposits on Mars?

References

  1. 1.0 1.1 1.2 1.3 1.4 1.5 1.6 1.7 1.8 B. Cairncross - Field guide to rocks and minerals of Southern Africa 2004. ISBN 978-1-86872-985-2 pp. 80-82
  2. 2.0 2.1 2.2 R. Webster & E.A. Jobbins - Gemmologists' compendium 7th ed. 2001. ISBN 978-0-7198-0291-1 p. 36.