Ethanol

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Ethanol molecule

Ethanol, also known as ethyl alcohol or grain alcohol, is the most common alcohol. Its formula is C2H5OH. It is clear and colorless. Ethanol is useful mixed into gasoline because it has a higher octane number than gasoline, reducing engine knocking.[1]

Ethanol is an ingredient in many beverages. It is a mild depressant when ingested. Besides its recreational use, ethanol is important to many industries and food preservation. Ethanol can be produced on Mars using In Situ Resources.

In situ Production

Ethanol production Paths

Ethanol is usually produced from biomass. Most plant material can be transformed to produce Ethanol.[1]

Fermentation

Ethanol is most easily produced from sugars by yeasts through fermentation.

Industrial Production via Carbon Dioxide

Argonne National Laboratory in Lemont Illinois has an electrocatalyst that efficiently converts carbon dioxide into ethanol. [2]

"The catalyst consists of atomically dispersed copper on a carbon-powder support. By an electrochemical reaction, this catalyst breaks down CO2 and water molecules and selectively reassembles the broken molecules into ethanol under an external electric field. The electrocatalytic selectivity, or 'Faradaic efficiency', of the process is over 90 percent. The catalyst also operates stably over extended operation at low voltage. The mechanism should also provide a foundation for development of highly efficient electrocatalysts for carbon dioxide conversion to a vast array of value-added chemicals.

Because CO2 is a stable molecule, transforming it into a different molecule is normally energy-intensive and costly. But the electrochemical process of CO2-to-ethanol conversion using the catalyst could be coupled to the electric grid to take advantage of the low-cost electricity available from renewable sources like solar and wind during off-peak hours. Because the process runs at low temperature and pressure, it can start and stop rapidly in response to the intermittent supply of the renewable electricity."

Industrial Production from Ethylene

Ethylene can be hydrated to produce Ethanol, although the reverse process, Ethylene production from Ethanol by dehydration, may be more common on Mars. Ethanol may also be produced form CO or CO2 and Water using a copper catalyst and electrolysis[3].[4]

Uses

Recreation and nutrition

Ingestion of excessive ethanol in food or drink causes intoxication. It is a mild depressant, and impairs judgement and reduces inhibitions. Managed use of ethanol may be used to raise morale. Ethanol ingestion may be restricted heavily in a settlement due to the risk to oneself and others.

Industrial Use

Ethanol is useful as a fuel. In contrast to most other chemical energy sources (or energy vectors, in this case), ethanol is relatively non-toxic and unreactive.

Ethanol is an effective solvent for many chemicals.

Food Preservation

Ethanol is used to preserve fruits and other foods.

References

  1. 1.0 1.1 “Ethanol.” n.d. U.S. Department of Energy: Alternative Fuels Data Center.
  2. Lina Chong (2021). Turning carbon dioxide into liquid fuel | Argonne National Laboratory. Anl.gov. Retrieved 25 November 2021, from https://www.anl.gov/article/turning-carbon-dioxide-into-liquid-fuel.
  3. Ethanol form CO and water https://www.technologyreview.com/2014/04/09/173425/a-less-resource-intensive-way-to-make-ethanol/
  4. 2020 upgraded process from CO2 https://scitechdaily.com/breakthrough-electrocatalyst-turns-carbon-dioxide-into-ethanol/