Hydrocarbon synthesis

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Hydrocarbon Synthesis is the generation of hydrocarbon molecules from other molecules containing hydrogen and carbon.

Methods

Natural Synthesis

Some bacteria and algae naturally produce hydrocarbons such as methane. Bioengineered microbes could be used in an industrial scale.

Artificial Synthesis

The building blocks of hydrocarbons, Hydrogen and Carbon, are readily available on Mars. Carbon Dioxide is the major component of the atmosphere. Water from the surface of Mars can be split through electrolysis. These building blocks are assembled through various chemical reactions.

Sabatier Reaction

Production of methane is possible via the Sabatier reaction:

CO2 + 4H2   ↔   CH4 + 2H2O

The forward reaction takes place in the presence of high temperatures and pressures, with a catalyst. Catalysts of nickel, ruthenium, or alumina can be used.

Reverse Water-Gas Shift Reaction

Carbon monoxide can be produced via the Reverse Water-Gas Shift Reaction:

CO2 + H2 → CO + H2O (deltaH = +9 kcal/mole)

The catalyst for this reaction is silica with 5% copper and a small amount of nickel.

Fischer-Tropsch Reaction

The Fischer-Tropsch reaction converts hydrogen and carbon monoxide into various hydrocarbons.

(2n+1)H2 + nCO → CnH(2n+2) + nH2O

'n' is any positive number.

Catalysts for this reaction include iron, cobalt, ruthenium, and nickel.