Difference between revisions of "Metal carbonyl"
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[[Carbon monoxide]] can form carbonyls of several metals: iron, nickel, chromium, osmium, iridium, ruthenium, rhenium, cobalt, and tungsten. | [[Carbon monoxide]] can form carbonyls of several metals: iron, nickel, chromium, osmium, iridium, ruthenium, rhenium, cobalt, and tungsten. | ||
| − | ==What is a Carbonyl?== | + | This page is about metal carbonyl's formed with [[Carbon monoxide]]. See the [[Carbonyl]] page for a discussion of all carbonyls. |
| − | Carbon monoxide | + | |
| − | == | + | ==What is a Metal Carbonyl?== |
| − | + | When [[Carbon monoxide]] gas is placed under pressure and heated, metals will 'dissolve' into the CO forming a liquid. Several carbon monoxide (CO) molecules will surround each metal atom. This is called a metal carbonyl. Iron carbonyl is a straw coloured liquid at room temperature and 1 bar pressure. | |
| + | |||
| + | Note that carbon monoxide (CO) is a colourless, odourless, poisonous gas. Care must be taken that it does not leak into human habitation areas. | ||
| + | |||
| + | See this link, <ref>https://en.wikipedia.org/wiki/Metal_carbonyl | Metal Carbonyls</ref> for the wikipedia page discussing them. | ||
| + | |||
| + | ==Use on Mars== | ||
| + | On Mars this has two main uses. First, dust or ground soil can be placed in a carbonyl reactor. CO is pumped in, and the gas is pressurized and heated. Metal on the surface of the dust grains will form a carbonyl extracting it from the rock particles. By changing the pressure and temperature, different metals can be pulled out in succession. When heated, these metals in solution will decompose back to solids, making ingots of pure metal. | ||
| + | |||
| + | The second use is to have a carbonyl in a 3D printer, and use a laser beam (or other heat source) to decompose the carbonyl and leave behind a trail of pure metal. Layers will build up, giving us a 3D printed part. Such a 3D printer might well be inside the reaction chamber that formed the metal carbonyl in the first place. | ||
| + | |||
| + | If it proves to be possible to build a flexible reactor that can handle several different metals (and print 3D parts) this would be a very useful item to bring to Mars. However, such a device has not yet been built. | ||
| + | |||
| + | ==Types of metal carbonyls== | ||
| + | |||
| + | *Titanium (surrounded by 6 CO molecules) | ||
| + | *Vanadium (surrounded by 6 CO molecules, forms a solid) | ||
| + | *Chromium (surrounded by 6 CO molecules) | ||
| + | *Manganese (surrounded by 6 CO molecules) | ||
| + | *Iron (surrounded by 5 or 6 CO molecules) | ||
| + | *Ruthenium (surrounded by 5 CO molecules) | ||
| + | *Nickle (surrounded by 4 CO molecules) | ||
| − | + | *Cobalt (2 cobalt atoms surrounded by 8 CO molecules, will form a carbonyl solid) <ref>https://en.wikipedia.org/wiki/Dicobalt_octacarbonyl#:~:text=Dicobalt%20octacarbonyl%20is%20an%20organocobalt,a%20family%20of%20hydroformylation%20catalysts.</ref> | |
| − | + | ==Industrial Uses of Carbonyls:== | |
| + | These are used in a variety of chemical industries. Some uses include: | ||
| − | Metal carbonyls can be used as a precursor to nano-particles. | + | *Metal carbonyls can be used as a precursor to nano-particles. |
| + | *They are useful in organic synthesis. | ||
| + | *They can be used as catalysts or catalyst precursors for organic chemistry. | ||
| + | *They can be used as precursors for the preparation of other organometallic complexes. | ||
| + | *They were used in the Mond process to refine [[Nickel]]. | ||
==References:== | ==References:== | ||
Latest revision as of 13:47, 29 September 2024
Carbon monoxide can form carbonyls of several metals: iron, nickel, chromium, osmium, iridium, ruthenium, rhenium, cobalt, and tungsten.
This page is about metal carbonyl's formed with Carbon monoxide. See the Carbonyl page for a discussion of all carbonyls.
Contents
What is a Metal Carbonyl?
When Carbon monoxide gas is placed under pressure and heated, metals will 'dissolve' into the CO forming a liquid. Several carbon monoxide (CO) molecules will surround each metal atom. This is called a metal carbonyl. Iron carbonyl is a straw coloured liquid at room temperature and 1 bar pressure.
Note that carbon monoxide (CO) is a colourless, odourless, poisonous gas. Care must be taken that it does not leak into human habitation areas.
See this link, [1] for the wikipedia page discussing them.
Use on Mars
On Mars this has two main uses. First, dust or ground soil can be placed in a carbonyl reactor. CO is pumped in, and the gas is pressurized and heated. Metal on the surface of the dust grains will form a carbonyl extracting it from the rock particles. By changing the pressure and temperature, different metals can be pulled out in succession. When heated, these metals in solution will decompose back to solids, making ingots of pure metal.
The second use is to have a carbonyl in a 3D printer, and use a laser beam (or other heat source) to decompose the carbonyl and leave behind a trail of pure metal. Layers will build up, giving us a 3D printed part. Such a 3D printer might well be inside the reaction chamber that formed the metal carbonyl in the first place.
If it proves to be possible to build a flexible reactor that can handle several different metals (and print 3D parts) this would be a very useful item to bring to Mars. However, such a device has not yet been built.
Types of metal carbonyls
- Titanium (surrounded by 6 CO molecules)
- Vanadium (surrounded by 6 CO molecules, forms a solid)
- Chromium (surrounded by 6 CO molecules)
- Manganese (surrounded by 6 CO molecules)
- Iron (surrounded by 5 or 6 CO molecules)
- Ruthenium (surrounded by 5 CO molecules)
- Nickle (surrounded by 4 CO molecules)
- Cobalt (2 cobalt atoms surrounded by 8 CO molecules, will form a carbonyl solid) [2]
Industrial Uses of Carbonyls:
These are used in a variety of chemical industries. Some uses include:
- Metal carbonyls can be used as a precursor to nano-particles.
- They are useful in organic synthesis.
- They can be used as catalysts or catalyst precursors for organic chemistry.
- They can be used as precursors for the preparation of other organometallic complexes.
- They were used in the Mond process to refine Nickel.
References:
"The Case For Mars, 2nd Edition", by Robert Zubrin, ISBN 9-781451-608113, pages 217 - 218.
// Discussion of ironpentacarbonyl.
