Atmospheric processing
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Atmospheric processing describes the extraction of substances out of the Martian atmosphere and the usage as raw material for further processing. Unlike surface and sub-surface mining, the atmospheric mining does not require the movement of large amounts of regolith or rock with heavy machinery, nor is expensive transport per rover or railroad necessary. The atmosphere can simply be sucked in through a pipe at every location, and the processing is done inside of buildings. Also, the maintenance of all the mining machinery is in-house, which is a major safety advantage.
Contents
Collection of Atmosphere
There are a number of ways the martian atmosphere can be processed to separate it into its individual components for process use. Mechanical compression is one of the main possibilities for large scale operations
In mechanical compression systems, a fan collects martian atmosphere and passes it through filters to separate out the dust. Then a compressor increases the pressure of the atmosphere to reach Earth atmospheric pressure. At this point water can be condensed out. Then a second compressor increases the pressure to the liquefaction point of CO2. The liquid CO2 is removed, and the leftover gases can be cooled further, to condense out into their liquis phases.
Process
Compression
Compression from the initial atmospheric pressure of 600 Pa to 1 bar (101 kPa, or Earth atmosphere) creates adequate conditions for the condensation of water, than can collect at the bottom of a pressure vessel and be removed. A second compressor increases the gas pressure to above 5,19 bar (520 kPa) , the liquefaction point of carbon dioxide. The liquid carbon dioxide can be separated by gravity from the other gasses. The compression ratio from 600 to 520 000 Pa is about 860 times.
Condensation
The change from a gas phase to a liquid phase is condensation. The compressors create a pressure environment where cooling the gas condensates one of the fractions of the atmosphere. The first gas to condensate out is water. Then the dry gas is cooled further to condense the carbon dioxide that can be removed by gravity. The other gases are removed by condensing the gases in further cooling stages. All of the cooled gas may be used for process purposes, or some of the CO2, or other gases, may be released back into the atmosphere. The expansion of the gas back to atmospheric pressure produces cooling that can be used to condensate out the atmospheric gases.
Results
Dust
The Martian atmosphere contains variable amounts of dust, which consists of minerals lifted by wind from the surface regolith. Electrostatic filters, cyclonic separators or dust collectors with fabric filters will be used to remove the dust to prevent it from damaging the equipment.
Water
The 0.03 % water vapor (H2O) is equivalent to about 10 % air humidity after adiabatic compression and cooling to around 1°C. A device similar to an air dehumidifier can be used to extract this water.
Carbon Dioxide
Carbon dioxide is the main part of the Martian atmosphere with 96 %. It can be used for the hydrocarbon synthesis, including the production of methane based fuel.
Nitrogen
The balance of the remaining gas after carbon dioxide condensation contains mostly nitrogen and argon. This mixture can serve as a buffer for oxygen to produce a breathable atmosphere. remaining traces of Carbon monoxide must be catalytically removed if the gas is to be used for the settlement atmosphere.
Nitrogen can be used to create ammonia and nitrates in fertilizer and as nitric acid in industry.
Argon
Argon is useful for industrial processes that must be performed in an inert atmosphere. It can also be used for electric rocket propulsion. It may be used as a complement for nitrogen in a martian settlement if it proves to be safe for that purpose.
